Use either the closest formatting options available in Excel to what is used in your WebGrid, or override this to use different formatting in the exported Excel file.
Formatting
Use the rich API of the WebGridExcelExporter to change, add, remove, or reorganize data taken from a WebGrid when exporting it to an Excel file.  You can also take data stored in other controls on your webpage and include this in the created Excel file.
Modify Data From WebGrid