Hello Ana,
To make a ListView SubColumn a checkbox column you should set the column’s DataType to System.Boolean.
this.ultraListView1.SubItemColumns[0].DataType = typeof(System.Boolean);
this.ultraListView1.SubItemColumns[1].SubItemAppearance.Image = "ColumnImage.png";
this.ultraListView1.Items[0].SubItems[1].Appearance.Image = "ItemImage.png";